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The Web Restrictions page allows you to configure what the user can access via the Internet It allows a parent to block objectionable content, but it s important to realize that the definition of objectionable varies from one parent to another Content can be blocked using one of the Web Restriction levels or by choosing categories based on content Figure 9-11 shows the available choices If desired a parent

Figure 9-11

can select the Block Some Websites or Content, and then add specific Web sites to the Allow and Block List

Medium Web content in the following categories is blocked: mature content, pornography, drugs, hate speech, and weapons Additionally, content that isn t rated is also blocked None All content is allowed Custom You pick the specific categories that you want to block, such as pornography, drugs, gambling, and more

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TIP Many corporations use a similar technology to block objectionable content at the proxy server For example, a company may decide they don t want employees gambling with company equipment on company time The company can subscribe with a third party to get a list of gambling Web sites and apply this list to the company s proxy server If an employee attempts to access one of the gambling Web sites, the attempt is blocked and logged In addition to blocking content by a specific Web restriction level or content category, you can also block or allow specific Web sites using the URL Figure 9-12 shows how you can specify exactly which Web sites are allowed or blocked

Atomic radius is a measure of the size of an atom The atomic radius is usually de ned as one-half the distance between two atomic nuclei, which assumes that the atoms are spherical and are in physical contact with each other The trend in atomic radii for main group elements is that the radii increase in size going down a column and the radii decrease in size going across a period from left to right The increase as you go down a period is easily explained because the outermost electron is in an orbital with a larger value of n, meaning a bigger orbital Li < Na < K < Rb < Cs because 2s < 3s < 4s < 5s < 6s There is a large jump in radius between a noble gas and the following alkali metal because the alkali metal introduces a new principal quantum number EXAMPLE: Ar [Ne]3s23p6 has a radius of 98 pm (1 p m = 10 12 m) K [Ar]4s1 has a radius that is over twice this big, 227 pm, because the last electron added to K is in the 4s orbital For ions, the radii of cations of the same charge show a regular increase when going down a column The same is true of anions of the same charge when going down a column Both of these effects are due to the increasing size of the orbitals Li+ (90 pm) < Na+ (116 pm) < K+ (153 pm) < Rb+ (166 pm) < Cs+ (181 pm) F (119 pm) < Cl (167 pm) < Br (182 pm) < I (206 pm) If you compare the radius of an ion to the radius of the atom from which that ion is derived, the cations are smaller than the parent atom because there is an excess of protons in the cation that can pull the electrons closer Anions are larger than the parent atom because there is an excess of electrons over protons Na+ (116 pm) < Na (186 pm) 11 p+ 10 e [Ne] 11 p+ 11 e [Ne]3s1 Cl (167 pm) > Cl (100 pm) 17 p+ 18 e [Ar] 17 p+ 17 e [Ne]3s23p5.

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