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Some polymers consisting entirely of head-to-head placements have been deliberately synthesized to determine if signi cant property differences exist compared to the head-totail polymers. The synthetic approach involves an appropriate choice of monomer for the particular H H polymer. For example, H H poly(vinyl chloride) is obtained by chlorination of 1,4-poly-1,3-butadiene,

concentration ($10 6 mol L 1 ) During the dark period that follows the pulse most of the primary radicals form propagating radicals, which then propagate, but some primary radicals terminate by coupling Normal coupling and disproportionation occur during the dark period, but a large fraction of propagating chain do not terminate because the cycle time is short The second laser pulse again produces a burst of primary radicals Most surviving propagating chains from the dark period between the rst and second laser pulses are almost instantaneously terminated by the high concentration of primary radicals formed in the second laser pulse But some of the propagating chains survive and continue to propagate during the second dark period.

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previous one. The 1980 s saw rates decline considerably despite the fact that French inflation was barely lower than it had been from 1965 to 1980. In France, open market short-term interest rates averaged below the quoted yields of rentes throughout the twentieth century, as they had during the latter decades of the nineteenth century. The difference was small in the second decade; it was unusually large in the 1940 s and 1950 s, but since then it has again become small. The preceding table of decennial averages may be used to compare French long-term rates with French short-term rates, and both with American and English rates. THE NETHERLANDS In the twentieth century the Netherlands held to its long tradition of political and financial stability. Neutral and prosperous during World War I, the country was overrun during World War II and soon thereafter lost the greater part of its empire. As a trading nation, it could not escape the effects of the violent political and economic disturbances that brought a succession of crises to its large neighbors. The value of the guilder, which was stable in the nineteenth century, fluctuated in the twentieth century. Long-Term Dutch Interest Rates. Chart 59 shows long and short decennial averages for the nineteenth and twentieth centuries. In the twentieth century interest rates were more stable in the Netherlands than in the

Some of the primary radicals in the second laser pulse initiate polymerization that proceeds in the second dark period, at the same time that some propagating chains from the rst dark period are propagating for a second dark period The process continues in a similar manner with each laser burst and subsequent dark period Suf cient laser pulses are used so that the amount of polymer produced is suf cient for analysis by size exclusion chromatography The amount of conversion is only about 2 3%, which means that the monomer concentration is essentially constant over the course of the experiment Some propagating chains terminate by normal coupling and/or disproportionation during the dark periods, but most do not Most of the polymer produced consists of propagating chains that have propagated for different multiples of the time of a dark period tp .

tp is essentially the same as the cycle time because the pulse width is so much shorter than tp Chains propagate for 1tp, 2tp , 3tp , and so on The degree of polymerization for chains terminated by primary radicals is given by.

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